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Issue 16, 1997
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Bis(N-piperidyl)carbene and its slow dimerisation totetrakis(N-piperidyl)ethene

Abstract

An unhindered bis(sec-amino)carbene can be generated by deprotonation of an amidinium ion with lithium diisopropylamide, and undergoes remarkably slow dimerisation to the corresponding tetraaminoethene.

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Article type: Paper
DOI: 10.1039/A703610H
Citation: Chem. Commun., 1997,0, 1513-1514
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    Bis(N-piperidyl)carbene and its slow dimerisation to tetrakis(N-piperidyl)ethene

    R. W. Alder and M. E. Blake, Chem. Commun., 1997, 0, 1513
    DOI: 10.1039/A703610H

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