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Issue 16, 1997
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Phosphorus monoxide as a terminal ligand


Dimethyldioxirane oxidation of phosphide PMo[N(R)Ar] 3 [R = C(CD 3 ) 2 Me, Ar = C 6 H 3 Me 2 -3,5] efficiently provides (OP)Mo[N(R)Ar] 3 , a complex shown by X-ray crystallography to contain a terminal phosphorus monoxide ligand, and which reacts with dimethylzirconocene to give addition of a Zr–Me bond across the phosphoryl moiety.

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Article type: Paper
DOI: 10.1039/A703105J
Citation: Chem. Commun., 1997,0, 1523-1524
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    Phosphorus monoxide as a terminal ligand

    M. J. A. Johnson, A. L. Odom and C. C. Cummins, Chem. Commun., 1997, 0, 1523
    DOI: 10.1039/A703105J

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