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Issue 18, 1997
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Cuprophilicity? a rare example of a ligand-unsupportedCuI–CuI interaction


The reaction of 1,1′-bis(2-pyridyl)octamethylferrocene (L) with [Cu(NCMe) 4 ]BF 4 in CH 2 Cl 2 affords [CuL][CuCl 2 ], the structure of which is determined by a single-crystal X-ray diffraction study; this reveals a remarkably short ligand-unsupported Cu I –Cu I contact of 281.0(2) pm.

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Article type: Paper
DOI: 10.1039/A702793A
Citation: Chem. Commun., 1997, 1723-1724
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    Cuprophilicity? a rare example of a ligand-unsupported CuI–CuI interaction

    U. Siemeling, U. Vorfeld, B. Neumann and H. Stammler, Chem. Commun., 1997, 1723
    DOI: 10.1039/A702793A

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