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Issue 12, 1997
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Axial ligation modulates the electron distribution in helicalcobalt complexes derived from octaethylbilindione

Saeed Attar,  Andrew Ozarowski,  Pamela M. Van Calcar,  Krzysztof Winkler  and  Alan L. Balch 

Abstract

Addition of pyridine to the four-coordinate cobalt(II) complex, [Co II (oebOx)]I 3 , which shows an EPR spectrum with well resolved Co hyperfine coupling, converts the complex into one with Co III /ligand radical structure and an EPR spectrum with g z = 1.98, and g xy = 2.02 and no cobalt hyperfine coupling.

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Article type: Paper
DOI: 10.1039/A701139C
Citation: Chem. Commun., 1997,0, 1115-1116
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    Axial ligation modulates the electron distribution in helical cobalt complexes derived from octaethylbilindione

    S. Attar, A. Ozarowski, P. M. Van Calcar, K. Winkler and A. L. Balch, Chem. Commun., 1997, 0, 1115
    DOI: 10.1039/A701139C

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