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Issue 18, 1997
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Flash vacuum pyrolysis of trifluoromethylateddiphenyldiazomethanes. Role of trifluoromethyl group in the arylcarbenerearrangement


Flash vacuum pyrolysis (350 °C/10 - 4 Torr) of the title diazo compounds gives trifluoromethylated fluorenes, indicating that the C–F bonds are completely unreactive toward carbene even in the gas phase at high temperatures.

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Article type: Paper
DOI: 10.1039/A700779E
Citation: Chem. Commun., 1997,0, 1745-1746
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    Flash vacuum pyrolysis of trifluoromethylated diphenyldiazomethanes. Role of trifluoromethyl group in the arylcarbene rearrangement

    H. Tomioka and K. Taketsuji, Chem. Commun., 1997, 0, 1745
    DOI: 10.1039/A700779E

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