Issue 2, 1997

Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH3)

Abstract

The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et 2 O adduct of AlH 3 , prepared from LiAlH 4 and H 2 SO 4 in Et 2 O at -80 °C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH 3 including unprecedented mono Al···H hydride bridging.

Article information

Article type
Paper

Chem. Commun., 1997, 245-246

Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH3)

P. C. Andrews, C. L. Raston, B. W. Skelton and A. H. White, Chem. Commun., 1997, 245 DOI: 10.1039/A607916D

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