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Issue 7, 1996
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1,5-Diborabicyclo[3.3.3]undecane; thermolysis of the product from hydroboration of triallylborane with triethylamine–borane

Roger W. Alder  and  Zhao Jin 

Abstract

Attempts to reproduce the reported preparation of 1,5-diborabicyclo [3.3.3] undecane 1 through hydroboration of triallylborane with triethylamine–borane, followed by thermolysis, have led to 1,5-dipropyl-1,5-diborocane 2 and other products, but the presence of 1 could not be detected by GC–MS. Treatment of triallylborane with monobromoborane, methanolysis and subsequent thermolysis gave 1,5-dimethoxy-1,5-diborocane 3 which could be converted to 2 by treatment with propylmagnesium bromide.

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Article type: Paper
DOI: 10.1039/P19960000657
Citation: J. Chem. Soc., Perkin Trans. 1, 1996,0, 657-660
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    1,5-Diborabicyclo[3.3.3]undecane; thermolysis of the product from hydroboration of triallylborane with triethylamine–borane

    R. W. Alder and Z. Jin, J. Chem. Soc., Perkin Trans. 1, 1996, 0, 657
    DOI: 10.1039/P19960000657

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