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Issue 5, 1996
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LiSb(edta)(H2O): a convenient preserser to LiSbS2 and LiSbO3

Bertrand Marrot,  Chantal Brouca-Cabarrecq  and  Alain Mosset 

Abstract

The synthesis and crystal structure of the edta complex LiSb(edta)(H2O) are reported (H4edta = ethylenediaminetetraacetic acid). The compound crystallizes in the monoclinic system. Sb(edta) entities are connected by cyclic [Li(COO)]2 dimers resulting in parallel layers stacked in the [110] direction. Pyrolysis of this complex under sulfur vapour between 700 and 850 °C leads to the mixed sulfide β-LiSbS2. Pyrolysis in air above 660 °C allows the preparation of the mixed oxide LiSbO3.

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Article type: Paper
DOI: 10.1039/JM9960600789
Citation: J. Mater. Chem., 1996,6, 789-793
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    LiSb(edta)(H2O): a convenient preserser to LiSbS2 and LiSbO3

    B. Marrot, C. Brouca-Cabarrecq and A. Mosset, J. Mater. Chem., 1996, 6, 789
    DOI: 10.1039/JM9960600789

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