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Issue 4, 1996
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Cyclopentadienyl metal teflate (OTeF5) complexes

Abstract

The [M(cp)2(OTeF5)2](M = Ti, Zr, Hf, Mo or W; cp =η5-C5H5) complexes have been readily prepared in halide–teflate metathesis reactions of [M(cp)2Cl2] with TeF5(OH). They extend the fluoride–teflate analogy to a new class of high-oxidation-state transition-metal complex. The compounds, which have been characterised by a combination of IR, mass spectrometry and multinuclear NMR spectroscopy, are shown to have polar metal–teflate interactions.

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Article type: Paper
DOI: 10.1039/DT9960000509
Citation: J. Chem. Soc., Dalton Trans., 1996,0, 509-511
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    Cyclopentadienyl metal teflate (OTeF5) complexes

    M. C. Crossman, E. G. Hope and G. C. Saunders, J. Chem. Soc., Dalton Trans., 1996, 0, 509
    DOI: 10.1039/DT9960000509

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