Issue 21, 1996

Synthesis and characterisation of the chloride-bridged copper–ruthenium cluster dianion [{Ru6Cu2C(CO)16}2Cl2]2–

Abstract

The mixed-metal ruthenium–copper cluster dianion [{Ru6Cu2C(CO)16}2]2–1 has been synthesised in quantitative yield from [Ru6C(CO)16]2– and CuCl; the crystal structure of the [N(PPh3)2]+ salt shows that the two Ru6 octahedra are linked by a rectangular planar arrangement of copper atoms two opposite edges of which are bridged by chlorine atoms.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 4033-4034

Synthesis and characterisation of the chloride-bridged copper–ruthenium cluster dianion [{Ru6Cu2C(CO)16}2Cl2]2–

M. A. Beswick, J. Lewis, P. R. Raithby and M. C. R. de Arellano, J. Chem. Soc., Dalton Trans., 1996, 4033 DOI: 10.1039/DT9960004033

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