Complexes of the form [Ru(C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CR′)2(L–L)2][L–L = R2PCH2CH2PR2; R = Me (dmpe) or Et (depe); R′= But, Ph, 4-HCCC6H4, 4-MeOC6H4 or 3,5-(F3C)2C6H3] were prepared by reaction of [RuCl2(L–L)2] or [RuH2(L–L)2] with terminal acetylenes in methanol solution. The spectroscopic data indicate that the acetylide groups adopt a trans stereochemistry across the metal centre. The crystal structure of [Ru(CCPh)2(dmpe)2] was determined.
L. D. Field, A. V. George, D. C. R. Hockless, G. R. Purches and A. H. White, J. Chem. Soc., Dalton Trans., 1996, 2011 DOI: 10.1039/DT9960002011
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...