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Issue 23, 1996
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Polymerisation of ethene by the novel titanium complex [Ti(Me3SiNCH2CH2NSiMe3)Cl2]; a metallocene analogue

Abstract

Reaction of the trimethylsilylated diamine ligand (Me3Si)NHCH2CH2NH(SiMe3) with titanium(IV) precursors affords the novel distorted-tetrahedral complex [Ti(Me3SiNCH2CH2NSiMe3)Cl2] which, when activated by methylaluminoxane, is an active ethene polymerisation catalyst.

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Article type: Paper
DOI: 10.1039/CC9960002623
Citation: Chem. Commun., 1996,0, 2623-2624
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    Polymerisation of ethene by the novel titanium complex [Ti(Me3SiNCH2CH2NSiMe3)Cl2]; a metallocene analogue

    S. Tinkler, R. J. Deeth, D. J. Duncalf and A. McCamley, Chem. Commun., 1996, 0, 2623
    DOI: 10.1039/CC9960002623

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