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Issue 22, 1996
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Self-assembly of metal complexes with cyclophane or plymeric chain structures about a 1,3,5-tris(diphenylphosphino)benzene core

Abstract

Two very different molecular shapes are formed using the ligand 1,3,5-tris(diphenylphosphino)benzene (L); polymeric chains form through Au⋯Au contacts in the crystals of [(ClAu)3L], while the metallocyclophane [(PtCl2)3L2] self assembles from five components when L and [PtCl2(cod)] are combined in a 2:3 molecular ratio.

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Article type: Paper
DOI: 10.1039/CC9960002597
Citation: Chem. Commun., 1996, 2597-2598
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    Self-assembly of metal complexes with cyclophane or plymeric chain structures about a 1,3,5-tris(diphenylphosphino)benzene core

    P. M. Van Calcar, M. M. Olmstead and A. L. Balch, Chem. Commun., 1996, 2597
    DOI: 10.1039/CC9960002597

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