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Issue 19, 1996
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The first structurally characterized organometallic nitrosyl porphyrin: structure of [Ru(ttp)(NO)(C6H4F-p)](ttp =meso-tetratolylporphyrinato dianion)

Abstract

Reaction of [Ru(ttp)(NO)Cl] with aryl or alkyl Grignard reagents gives [Ru(ttp)(NO)R](R = C6H4F-p, Me); the Ru–C bond in [Ru(ttp)(NO)Me] undergoes insertion by SO2, and the structure of [Ru(ttp)(NO)(C6H4F-p)] is determined by X-ray crystallography.

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Article type: Paper
DOI: 10.1039/CC9960002283
Citation: Chem. Commun., 1996,0, 2283-2284
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    The first structurally characterized organometallic nitrosyl porphyrin: structure of [Ru(ttp)(NO)(C6H4F-p)](ttp =meso-tetratolylporphyrinato dianion)

    S. J. Hodge, L. Wang, M. A. Khan, V. G. Young and G. B. Richter-Addo, Chem. Commun., 1996, 0, 2283
    DOI: 10.1039/CC9960002283

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