Issue 7, 1996

Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand

Abstract

The chiral oxazolylferrocene-phosphine hybrid ligand(DIPOF) is a very effective ligand for IrI-catalysed asymmetric hydrosilylation of simple ketones to give the corresponding sec-alcohols(up to 96% ee) after acid hydrolysis.

Article information

Article type
Paper

Chem. Commun., 1996, 847-848

Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand

Y. Nishibayashi, K. Segawa, H. Takada, K. Ohe and S. Uemura, Chem. Commun., 1996, 847 DOI: 10.1039/CC9960000847

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