cis-[Ru(dmpe)2H2] reacts at –78 °C with hexafluorobenzene to generate the pentafluorophenyl hydride complex,trans-[Ru(dmpe)2(C6F5)H]; reaction also takes place with C6F5H, C6F5CF3, C6F5OCH3,1,2,3,4-C6F4H2 and 1,2,3-C6F3H3 to yield products from C–F insertion exclusively.
M. K. Whittlesey, R. N. Perutz and M. H. Moore, Chem. Commun., 1996, 787 DOI: 10.1039/CC9960000787
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