Schiff-base compartmental macrocyclic complexes

Andrew J. Atkins; Daniel Black; Alexander J. Blake; Armando Marin-Becerra; Simon Parsons; Lena Ruiz-Ramirez; Martin Schröder

doi:10.1039/CC9960000457

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Chemical Communications

Issue 4, 1996

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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Schiff-base compartmental macrocyclic complexes

Andrew J. Atkins, Daniel Black, Alexander J. Blake, Armando Marin-Becerra, Simon Parsons, Lena Ruiz-Ramirez and Martin Schröder

Chem. Commun., 1996, 457-464

DOI: 10.1039/CC9960000457

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Abstract
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The synthesis of a range of new compartmental macrocyclic complexes based on 2,6-diformyl and -diketo phenol groups is described. The metal-free ligands have been prepared and structurally characterised for the first time, and this has led to the synthesis of novel cubane and platinum-group metal complexes. The synthesis of related dithiophenolato-bridged compartmental complexes of Ni^II, Cu^II and Zn^II has been achieved and the relevance of these species to metalloproteins is discussed.

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Andrew J. Atkins
Daniel Black
Alexander J. Blake
Armando Marin-Becerra
Simon Parsons
Lena Ruiz-Ramirez
Martin Schröder

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