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Issue 22, 1996
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Aggregation of tripodal thallium(I) amides through weak TlI⋯TlI interactions

Konrad W. Hellmann,  Lutz H. Gade,  Ian J. Scowen  and  Mary McPartlin 

Abstract

Metal exchange between the lithium amide MeSi[SiMe2N-(Li)But]3 and TlCl yields the corresponding thallium amide MeSi[SiMe2N(Tl)But]3 1 which aggregates in the solid through weak attractive Tl⋯Tl interactions to form infinite molecular chains; competing redox chemistry leads to the dimetallated species HC[SiMe2N(Tl)But]2[SiMe2NHBut] 2 in the analogous metal-exchange process involving the trisilylmethane derivative.

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Article type: Paper
DOI: 10.1039/CC9960002515
Citation: Chem. Commun., 1996,0, 2515-2516
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    Aggregation of tripodal thallium(I) amides through weak TlI⋯TlI interactions

    K. W. Hellmann, L. H. Gade, I. J. Scowen and M. McPartlin, Chem. Commun., 1996, 0, 2515
    DOI: 10.1039/CC9960002515

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