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Issue 13, 1996
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Reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] to form the unique methyl-bridged compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2]

Abstract

The synthesis and structural characterization of the novel transition-metal amido/alkyl compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2] 1 via the reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] are reported; 1 features a unique Mn(µ-Me)2Mn type of bridged structure stabilized by Mn–Me interactions involving a methyl group from AlMe3.

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Article type: Paper
DOI: 10.1039/CC9960001573
Citation: Chem. Commun., 1996,0, 1573-1574
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    Reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] to form the unique methyl-bridged compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2]

    M. Niemeyer and P. P. Power, Chem. Commun., 1996, 0, 1573
    DOI: 10.1039/CC9960001573

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