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Issue 10, 1996
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Combining carbaboranes with transition-metal clusters; synthesis and X-ray structure analysis of a 1,2,3,4,5-pentamethyl-2,3,4,5-tetracarba-nido-hexaborane(6) derivative

Max Herberhold,  Uwe Bertholdt,  Wolfgang Milius,  Alexandra Glöckle  and  Bernd Wrackmeyer 

Abstract

The 6-bromopentamethyl- and 1,6-dibromo-2,5-dibutyl-3,4-diethyl-2,3,4,5-tetracarba-nido-hexaboranes(6)(1 and 2) react with the tetrahedrane anion [Fe2(CO)6(µ-SN)]– 3 to form the N-{6-[2,3,4,5-tetracarba-nido-hexaborane(6)-yl]} hexacarbonyldiferraazathia tetrahedranes 4 and 5, respectively, in which two different cages are directly connected through a B–N bond; the X-ray crystal structure of 4 provides the first example of the structure of an ‘undisturbed’ 2,3,4,5-tetracarba-nido-hexaborane(6).

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Article type: Paper
DOI: 10.1039/CC9960001219
Citation: Chem. Commun., 1996,0, 1219-1220
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    Combining carbaboranes with transition-metal clusters; synthesis and X-ray structure analysis of a 1,2,3,4,5-pentamethyl-2,3,4,5-tetracarba-nido-hexaborane(6) derivative

    M. Herberhold, U. Bertholdt, W. Milius, A. Glöckle and B. Wrackmeyer, Chem. Commun., 1996, 0, 1219
    DOI: 10.1039/CC9960001219

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