Issue 14, 1995

Synthesis and X-ray crystal structure of 1,3,5-tris(fluoren-9-ylidenemethyl)benzene: towards a C48-fragment of [60]-fullerene

Abstract

Three-fold, stereoselective Wittig reactions between benzene-1, 3, 5-tricarbaldehyde 4 and fluoren-9-ylidene(triphenyl)phosphine 5 furnished an interesting C48-hydrocarbon ofC3symmetry whose crystal structure has been determined.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1995, 1787-1788

Synthesis and X-ray crystal structure of 1,3,5-tris(fluoren-9-ylidenemethyl)benzene: towards a C48-fragment of [60]-fullerene

G. Mehta, K. V. Rao and K. Ravikumar, J. Chem. Soc., Perkin Trans. 1, 1995, 1787 DOI: 10.1039/P19950001787

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