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Issue 7, 1995
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Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

Abstract

The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1]octane framework to an isomeric bicyclo[3.2.1]octene skeleton via a bicyclo[2.2.2]octane derivative.

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Article type: Paper
DOI: 10.1039/P19950000839
Citation: J. Chem. Soc., Perkin Trans. 1, 1995, 839-846
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    Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

    N. Selvakumar, S. N. Janaki, K. Pramod and G. S. R. S. Rao, J. Chem. Soc., Perkin Trans. 1, 1995, 839
    DOI: 10.1039/P19950000839

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