Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

Natesan Selvakumar; Seenivasaga N. Janaki; Kakumanu Pramod; G. S. R. Subba Rao

doi:10.1039/P19950000839

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Journal of the Chemical Society, Perkin Transactions 1

Issue 7, 1995

Perkin Transactions 1 ceased publication in 2002. Organic & Biomolecular Chemistry is the RSC's journal for high-quality, original organic chemistry research.

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Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

Natesan Selvakumar, Seenivasaga N. Janaki, Kakumanu Pramod and G. S. R. Subba Rao

J. Chem. Soc., Perkin Trans. 1, 1995, 839-846

DOI: 10.1039/P19950000839

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Abstract
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The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1]octane framework to an isomeric bicyclo[3.2.1]octene skeleton via a bicyclo[2.2.2]octane derivative.

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Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

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Journal of the Chemical Society, Perkin Transactions 1

Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

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