Issue 11, 1995

Trapping of translocated radicals by tetrathiafulvalene radical cation

Abstract

Aryl radicals are generated by electron transfer from tetrathiafulvalene to arenediazonium salts. The aryl radicals are translocated into alkyl radicals which undergo a C–S or C–C bond formation to tetrathiafulvalene radical cation, depending on the nucleophilicity/electrophilicity of the translocated carbon radical.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1995, 1349-1358

Trapping of translocated radicals by tetrathiafulvalene radical cation

J. A. Murphy and S. J. Roome, J. Chem. Soc., Perkin Trans. 1, 1995, 1349 DOI: 10.1039/P19950001349

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