In the presence of lead dichloride and a metallic gallium bimetal redox system, carbonyl compounds reacted with ethyl trichloroacetate and iodoacetonitrile to afford ethyl β-substituted α,α-dichloropropionates and β-hydroxy nitriles, respectively, in moderate to excellent yields.
X. Zhang, Y. Han, W. Tao and Y. Huang, J. Chem. Soc., Perkin Trans. 1, 1995, 189 DOI: 10.1039/P19950000189
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