Nanoscale Ag–Pd and Cu–Pd alloys

H. N. Vasan; C. N. R. Rao

doi:10.1039/JM9950501755

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Journal of Materials Chemistry

Issue 10, 1995

Journal of Materials Chemistry was published between 1991 and 2012. From issue 1, 2013, it was replaced by three new journals: Journal of Materials Chemistry A, B and C

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Nanoscale Ag–Pd and Cu–Pd alloys

H. N. Vasan and C. N. R. Rao

J. Mater. Chem., 1995,5, 1755-1757

DOI: 10.1039/JM9950501755

This article is part of themed collection: Molecular Conductors

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Abstract
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Nanoparticles of Ag–Pd and Cu–Pd alloys with diameters in the 5–40 nm range have been prepared over the entire range of compositions, by employing the heterogeneous reaction of dry methanol or ethanol with intimate mixtures of AgNO₃+ PdO_x and CuO_x+ PdO_x, respectively. The nanoscale alloys have been characterized by energy-dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM) and X-ray diffraction (XRD). All the alloy particles possess the fcc structure and can be obtained in bulk quantities.

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