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Issue 12, 1995
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Facile synthesis of Sn4N4 cubanes; syntheses and structures of [Sn(NC6H11)]4 and [Sn(2-NCH2C5H4N)]4

Robert E. Allan,  Michael A. Beswick,  Andrew J. Edwards,  Michael A. Paver,  Moira-Ann Rennie,  Paul R. Raithby  and  Dominic S. Wright 

Abstract

The low-temperature reaction of Sn(NMe2)2 with primary amines (NH2R)(1 : 1 equivalents) is a general route by which imido tin(II) cubanes [Sn(NR)]4 can be prepared. It has been exemplified by the direct reactions of the relatively non-acidic primary amines NH2(C6H11) and 2-H2NCH2C5H4N, producing the cubanes [Sn(NC6H11)]41 and [Sn(2-NCH2C5H4N)]42. The structures of both complexes have been established by X-ray crystallography.

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Article type: Paper
DOI: 10.1039/DT9950001991
Citation: J. Chem. Soc., Dalton Trans., 1995,0, 1991-1994
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    Facile synthesis of Sn4N4 cubanes; syntheses and structures of [Sn(NC6H11)]4 and [Sn(2-NCH2C5H4N)]4

    R. E. Allan, M. A. Beswick, A. J. Edwards, M. A. Paver, M. Rennie, P. R. Raithby and D. S. Wright, J. Chem. Soc., Dalton Trans., 1995, 0, 1991
    DOI: 10.1039/DT9950001991

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