Protonation at one of the phenylacetylide substituents of the allylic complexes [W(cp)(CO)2{η3H2CC[C(C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CPh)2]CH2R}](cp =η-C5H5), including the first cationic tungsten–ruthenium allylic vinylidene complex, R = C(Ph)![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CRu(cp)(PPh3)2(crystal structure), gave η4-vinylallene complexes.
D. Chen, P. Ting, Y. Lin, G. Lee and Y. Wang, J. Chem. Soc., Dalton Trans., 1995, 3561 DOI: 10.1039/DT9950003561
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