Optically active naphthalene–Cr(CO)3 complexes via diastereoselective carbene annulation and haptotropic metal migration

Karl Heinz Dötz; Christine Stinner; Martin Nieger

doi:10.1039/C39950002535

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Optically active naphthalene–Cr(CO)₃ complexes via diastereoselective carbene annulation and haptotropic metal migration

Karl Heinz Dötz , Christine Stinner and Martin Nieger

J. Chem. Soc., Chem. Commun., 1995, 2535-2536

DOI: 10.1039/C39950002535

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Abstract
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Pentacarbonyl[(+)- and (–)-menthyloxycarbene] complexes of chromium react with 3, 3-dimethylbut-1-yne diastereoselectively to give optically active naphthalene–Cr(CO)₃ complexes which upon warming undergo an intramolecular haptotropic migration of the metal fragment.

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Journal of the Chemical Society, Chemical Communications

Optically active naphthalene–Cr(CO)₃ complexes via diastereoselective carbene annulation and haptotropic metal migration

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