Preparation of zeolites incorporating molybdenum sulfide clusters with high C2 hydrocarbon selectivity in Co–H2 reactions

Mitsugu Taniguchi; Youichi Ishii; Takashi Murata; Takashi Tatsumi; Masanobu Hidai

doi:10.1039/C39950002533

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Preparation of zeolites incorporating molybdenum sulfide clusters with high C₂ hydrocarbon selectivity in Co–H₂ reactions

Mitsugu Taniguchi , Youichi Ishii , Takashi Murata , Takashi Tatsumi and Masanobu Hidai

J. Chem. Soc., Chem. Commun., 1995, 2533-2534

DOI: 10.1039/C39950002533

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Abstract
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The incomplete cubane-type cluster, [Mo₃S₄(H₂O)₉]⁴⁺, and the complete cubane-type cluster, [Mo₃NiS₄(H₂O)₉Cl]³⁺, are incorporated into 12-membered ring zeolites by ion exchange, leading to catalysts which are highly selective for C₂ formation from CO–H₂.

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Mitsugu Taniguchi
Youichi Ishii
Takashi Murata
Takashi Tatsumi
Masanobu Hidai

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Journal of the Chemical Society, Chemical Communications

Preparation of zeolites incorporating molybdenum sulfide clusters with high C₂ hydrocarbon selectivity in Co–H₂ reactions

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