Electrospray mass spectrometry of neutral metal carbonyl complexes using silver(I) ions for ionisation

William Henderson; Brian K. Nicholson

doi:10.1039/C39950002531

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Electrospray mass spectrometry of neutral metal carbonyl complexes using silver(I) ions for ionisation

William Henderson and Brian K. Nicholson

J. Chem. Soc., Chem. Commun., 1995, 2531-2532

DOI: 10.1039/C39950002531

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Abstract
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Silver(I) ions are used for chemical ionisation in the electrospray mass spectrometric analysis of neutral metal carbonyls such as [M₃(CO)₁₂](M = Ru, Os), [Re₂(CO)₁₀] or [SiFe₄(CO)₁₆] in a variety of solvents (MeOH, PrⁱOH, THF, or MeCN–H₂O).

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Journal of the Chemical Society, Chemical Communications

Electrospray mass spectrometry of neutral metal carbonyl complexes using silver(I) ions for ionisation

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