Alane reduction of selenium and tellurium: tertiary amine stabilised dimeric chalcogenides, trans-[{Me3N(H)Al(µ-E)}2](E = Se, Te)

Michael G. Gardiner; Colin L. Raston; Vicki-Anne Tolhurst

doi:10.1039/C39950002501

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Alane reduction of selenium and tellurium: tertiary amine stabilised dimeric chalcogenides, trans-[{Me₃N(H)Al(µ-E)}₂](E = Se, Te)

Michael G. Gardiner , Colin L. Raston and Vicki-Anne Tolhurst

J. Chem. Soc., Chem. Commun., 1995, 2501-2502

DOI: 10.1039/C39950002501

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Abstract
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Elemental selenium or tellurium react with trimethylamine alane, [Me₃NAlH₃], in toluene affording the bis-trimethylamine adducts of the dimeric chalcogenidoalanes, [{HAl(µ-E)}₂](E = Se, Te) isolated as the trans-isomers; ab initio molecular orbital calculations on model species show that N-donor Lewis-base solvated dimeric species are the energetically most favourable structures for these chalcogenidoalane species.

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Journal of the Chemical Society, Chemical Communications

Alane reduction of selenium and tellurium: tertiary amine stabilised dimeric chalcogenides, trans-[{Me₃N(H)Al(µ-E)}₂](E = Se, Te)

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