Switching of two amine ligands via an SN2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

Shinji Toyota; Tadahiro Futawaka; Hiroshi Ikeda; Michinori Ōki

doi:10.1039/C39950002499

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Switching of two amine ligands via an S_N2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

Shinji Toyota , Tadahiro Futawaka , Hiroshi Ikeda and Michinori Ōki

J. Chem. Soc., Chem. Commun., 1995, 2499-2500

DOI: 10.1039/C39950002499

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Abstract
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Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.

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Journal of the Chemical Society, Chemical Communications

Switching of two amine ligands via an S_N2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

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