Mutual isomerization of η1-allenyl and η1-propargyl complexes of platinum via a five-coordinate η3-allenyl/propargyl intermediate

Sensuke Ogoshi; Yoshiaki Fukunishi; Ken Tsutsumi; Hideo Kurosawa

doi:10.1039/C39950002485

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Mutual isomerization of η¹-allenyl and η¹-propargyl complexes of platinum via a five-coordinate η³-allenyl/propargyl intermediate

Sensuke Ogoshi , Yoshiaki Fukunishi , Ken Tsutsumi and Hideo Kurosawa

J. Chem. Soc., Chem. Commun., 1995, 2485-2486

DOI: 10.1039/C39950002485

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Abstract
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The reversible spontaneous isomerization between η¹-allenyl and η¹-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate η³-allenyl/propargyl intermediate.

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Journal of the Chemical Society, Chemical Communications

Mutual isomerization of η¹-allenyl and η¹-propargyl complexes of platinum via a five-coordinate η³-allenyl/propargyl intermediate

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