Characterization of persistent α,ω-diphenyl substituted allyl cations within monodirectional acid zeolites

María L. Cano; Vicente Fornés; Hermenegildo García; Miguel A. Miranda; Julia Pérez-Prieto

doi:10.1039/C39950002477

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Journal of the Chemical Society, Chemical Communications

Issue 24, 1995

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Characterization of persistent α,ω-diphenyl substituted allyl cations within monodirectional acid zeolites

María L. Cano , Vicente Fornés , Hermenegildo García , Miguel A. Miranda and Julia Pérez-Prieto

J. Chem. Soc., Chem. Commun., 1995, 2477-2478

DOI: 10.1039/C39950002477

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Abstract
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Two α,ω-diphenyl substituted allylic cations are generated within ZSM-5 and mordenite as persistent species by adsorption of 1-acetoxy-1,3-diphenylpropane and 1,5-diacetoxy-1,5-diphenylpentane onto the H⁺-form of these zeolites; the diffuse reflectance spectra of these highly coloured samples (orange or pink) matches the very characteristic absorption spectra of these allyl cations in homogeneous solution; the non-acidic Na⁺-form of these zeolites does not have the same effect.

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María L. Cano
Vicente Fornés
Hermenegildo García
Miguel A. Miranda
Julia Pérez-Prieto

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Journal of the Chemical Society, Chemical Communications

Characterization of persistent α,ω-diphenyl substituted allyl cations within monodirectional acid zeolites

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