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Issue 20, 1995
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High esterolytic activity of a novel water-soluble polymer catalyst imprinted by a transition-state analogue

Abstract

A novel water-soluble polymer catalyst containing a L-histidyl group as a catalytic site, prepared by imprinting of a transition-state analogue of phenyl 1-benzyloxycarbonyl-3-methylpentyl phosphonate, accelerates the substrate-specific esterolysis of p-nitrophenyl N-(benzyloxycarbonyl)-L-leucinate (Z-L-Leu-PNP) in 10 vol% Me2O–Tris buffer (pH 7. 15) at 293–308 K.

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Article type: Paper
DOI: 10.1039/C39950002143
Citation: J. Chem. Soc., Chem. Commun., 1995,0, 2143-2144
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    High esterolytic activity of a novel water-soluble polymer catalyst imprinted by a transition-state analogue

    K. Ohkubo, Y. Funakoshi, Y. Urata, S. Hirota, S. Usui and T. Sagawa, J. Chem. Soc., Chem. Commun., 1995, 0, 2143
    DOI: 10.1039/C39950002143

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