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Issue 8, 1995
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Lithium anilide complexed by pmdeta: expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium

Abstract

Lithium structural chemistry continues to surprise as highlighted here by the reaction of BunLi, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.

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Article type: Paper
DOI: 10.1039/C39950000891
Citation: J. Chem. Soc., Chem. Commun., 1995,0, 891-892
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    Lithium anilide complexed by pmdeta: expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium

    D. Barr, W. Clegg, L. Cowton, L. Horsburgh, F. M. Mackenzie and R. E. Mulvey, J. Chem. Soc., Chem. Commun., 1995, 0, 891
    DOI: 10.1039/C39950000891

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