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Issue 5, 1995
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Air oxidation of a manganese(III) thioether chelate affords the first manganese(III) dihydrosalen complex with a pendant sulfoxide ligand

Abstract

The aerobic oxidation of the manganese(III) dihydrosalen-thioether chelate rac-1 affords the novel manganese(III) sulfoxide complex rac-2; X-ray structural analysis of the latter reveals that only one of the two possible diastereomeric oxidation products is present in the crystal.

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Article type: Paper
DOI: 10.1039/C39950000535
Citation: J. Chem. Soc., Chem. Commun., 1995,0, 535-536
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    Air oxidation of a manganese(III) thioether chelate affords the first manganese(III) dihydrosalen complex with a pendant sulfoxide ligand

    A. Berkessel, M. Bolte and T. Schwenkreis, J. Chem. Soc., Chem. Commun., 1995, 0, 535
    DOI: 10.1039/C39950000535

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