Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)5PPh2]2(µ-C5H2S3)
Abstract
The first 6a-thiathiophthen metal complex was prepared by treating M(CO)5[PPh2CS2CH2CCH] with a catalytic amount of secondary amine or tertiary amine; the structure of the 6a-thiathiophthen molybdenum complex is confirmed by an X-ray diffraction analysis.