Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)5PPh2]2(µ-C5H2S3)

Kuang-Hway Yih; Ying-Chih Lin; Gene-Hsiang Lee; Yu Wang

doi:10.1039/C39950000223

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Journal of the Chemical Society, Chemical Communications

Issue 2, 1995

Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)₅PPh₂]₂(µ-C₅H₂S₃)

Kuang-Hway Yih, Ying-Chih Lin, Gene-Hsiang Lee and Yu Wang

J. Chem. Soc., Chem. Commun., 1995, 223-224

DOI: 10.1039/C39950000223

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Abstract
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The first 6a-thiathiophthen metal complex was prepared by treating M(CO)₅[PPh₂CS₂CH₂C [triple bond, length half m-dash] CH] with a catalytic amount of secondary amine or tertiary amine; the structure of the 6a-thiathiophthen molybdenum complex is confirmed by an X-ray diffraction analysis.

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Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)₅PPh₂]₂(µ-C₅H₂S₃)

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Journal of the Chemical Society, Chemical Communications

Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)5PPh2]2(µ-C5H2S3)

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Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)₅PPh₂]₂(µ-C₅H₂S₃)