A remarkable difference is observed in the rates of [3,3]-sigmatropic rearrangement of aryl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranosides 1 and 2; the slower reactivity of the α-isomers is consistent with AM1 calculated transition state energetics of model systems.
Fetching data from CrossRef. This may take some time to load.
Journal of the Chemical Society, Perkin Transactions 2
- Information Point