Stable benzene-fused triselenide compounds, 4,7-diisopropylbenzo[1,2-d][1,2,3]triselenole 2 and its radical cation salt, 4,7-diisopropylbenzo[1,2-d][1,2,3]triselenolium hexafluorophosphate 3, are prepared and undergo novel one-electron redox reactions.
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