SCHEDULED MAINTENANCE
Soft-chemical oxidation of KTiOPO4-like KMV0.5TiIII0.5OPO4(M = Nb, Ta) using chlorine in CHCl3 is accompanied by partial deintercalation of potassium, yielding K0.5MV0.5TiIV0.5OPO4 compounds which are new non-linear optical materials that exhibit efficient second-harmonic generation of 1064 nm radiation, as does KTiOPO4.
K. K. Rangan, B. R. Prasad, C. K. Subramanian and J. Gopalakrishnan, J. Chem. Soc., Chem. Commun., 1994, 141 DOI: 10.1039/C39940000141
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