Issue 17, 1994

The stereochemical course of substitution of sulfur by oxygen nucleophiles in five-membered cyclic phosphorothioates

Abstract

The replacement of non-bridging sulfur in five-membered cyclic phosphorothioates by oxygen nucleophiles in the presence of bromine occurs with retention of configuration and has allowed the 31P NMR signals of the diastereoisomeric tert-butyldiphenyl silyl esters of 2′,3′-cyclic adenosine monophosphate to be assigned.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1947-1948

The stereochemical course of substitution of sulfur by oxygen nucleophiles in five-membered cyclic phosphorothioates

G. Lowe and M. Thelin, J. Chem. Soc., Chem. Commun., 1994, 1947 DOI: 10.1039/C39940001947

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