Issue 2, 1994

Insertion of a transition metal fragment into a heptaantimonide(3–) anion: synthesis and structure of [Sb7Mo(CO)3]3–

Abstract

Reaction of Na2Sb7 with Mo(bipy)(CO)4(bipy = bipyridyl) and 2,2,2-crypt(4,7,13,16,21,24-hexaoxa-1,10-diazobicyclo-[8.8.8]hexacosane) in ethylenediamine results in the formation of [Na(2,2,2-crypt)]3[Sb7Mo(CO)3], whose structure has been determined crystallographically.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 217-219

Insertion of a transition metal fragment into a heptaantimonide(3–) anion: synthesis and structure of [Sb7Mo(CO)3]3–

U. Bolle and W. Tremel, J. Chem. Soc., Chem. Commun., 1994, 217 DOI: 10.1039/C39940000217

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