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Issue 10, 1993
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A single transition state in nucleophilic aromatic substitution: reaction of phenolate ions with 2-(4-nitrophenoxy)-4,6-dimethoxy-1,3,5-triazine in aqueous solution

Abstract

The absence of curvature in the Brønsted dependence for displacement of 4-nitrophenolate ion from the title ether by phenolate ion nucleophiles with pKas well below and above that of the leaving group is consistent with a single step mechanism.

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Article type: Paper
DOI: 10.1039/P29930001703
Citation: J. Chem. Soc., Perkin Trans. 2, 1993,0, 1703-1704
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    A single transition state in nucleophilic aromatic substitution: reaction of phenolate ions with 2-(4-nitrophenoxy)-4,6-dimethoxy-1,3,5-triazine in aqueous solution

    A. H. M. Renfrew, J. A. Taylor, J. M. J. Whitmore and A. Williams, J. Chem. Soc., Perkin Trans. 2, 1993, 0, 1703
    DOI: 10.1039/P29930001703

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