Phenolic oxidations with phenyliodonium diacetate

Andrew Pelter; Said M. A. Elgendy

doi:10.1039/P19930001891

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Journal of the Chemical Society, Perkin Transactions 1

Issue 16, 1993

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Phenolic oxidations with phenyliodonium diacetate

Andrew Pelter and Said M. A. Elgendy

J. Chem. Soc., Perkin Trans. 1, 1993, 1891-1896

DOI: 10.1039/P19930001891

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Abstract
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Phenyliodonium diacetate (PIDA) in methanol interacts smoothly with phenols to yield p-quinones, o-quinones, 4,4-dialkoxycyclohexa-2,5-dienones or-4-alkyl-4-alkoxycyclohexa-2,5-dienones, dependant on the constitution of the phenolic substrate. The reactions proceed in mild conditions and good yields and are synthetically useful.

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Journal of the Chemical Society, Perkin Transactions 1

Phenolic oxidations with phenyliodonium diacetate

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