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Issue 10, 1993
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Analysis of product Doppler-broadened profiles generated from photoinitiated bimolecular reactions

Abstract

This paper, which is the companion to the experimental paper (M. Brouard, S. P. Duxon, P. A. Enriquez and J. P. Simons, J. Chem. Soc., Faraday Trans., 1993, 89, 1435) in this issue, is divided into two parts. In the first, equations for the laboratory (LAB) velocity distribution of products generated via photoionitiated bimolecular reaction are presented. These equations provide the basis for numerical simulation of these distributions from assumed forms for the centre-of-mass (CM) differential cross-section: the results may be compared directly with those derived experimentally via Fourier-transform Doppler 1 + 1 LIF or REMPI spectroscopy. The latter inversion technique is described in detail in the second part of the paper.

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Article type: Paper
DOI: 10.1039/FT9938901427
Citation: J. Chem. Soc., Faraday Trans., 1993,89, 1427-1434
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    Analysis of product Doppler-broadened profiles generated from photoinitiated bimolecular reactions

    F. J. Aoiz, M. Brouard, P. A. Enriquez and R. Sayos, J. Chem. Soc., Faraday Trans., 1993, 89, 1427
    DOI: 10.1039/FT9938901427

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