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Issue 14, 1993
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Synthesis, structure and electrochemistry of [Pt([10]aneS3)2][PF6]2([10]aneS3= 1,4,7-trithiacyclodecane)

Alexander J. Blake,  Rhona D. Crofts  and  Martin Schröder 

Abstract

The orange complex [Pt([10]aneS3)2][PF6]2([10]aneS3= 1,4,7-trithiacyclodecane) is centrosymmetric with primary S4 co-ordination, Pt–S(5) 2.297(4), Pt-S(8) 2.309(4), Å, with long-range interactions to the two remaining S-donors, Pt ⋯ S(1) 3.233(4)Å; [Pt([10]aneS3)2]2+ shows a broad two-electron oxidation centred at E½=+0.35 V (vs. ferrocene–ferrocenium) assigned to a PtII–PtIV couple.

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Article type: Paper
DOI: 10.1039/DT9930002259
Citation: J. Chem. Soc., Dalton Trans., 1993,0, 2259-2260
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    Synthesis, structure and electrochemistry of [Pt([10]aneS3)2][PF6]2([10]aneS3= 1,4,7-trithiacyclodecane)

    A. J. Blake, R. D. Crofts and M. Schröder, J. Chem. Soc., Dalton Trans., 1993, 0, 2259
    DOI: 10.1039/DT9930002259

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