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Issue 15, 1993
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Regio- and stereo-selective ring opening of epoxides with amide cuprate reagents

Abstract

Amide cuprate reagents attack the less hindered carbon atom of epoxides to give 1,2-amino alcohols in good yields; this procedure is applied to the synthesis of an aziridine alcohol bearing a carborane framework which is a potentially useful 10B carrier for boron neutron capture therapy.

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Article type: Paper
DOI: 10.1039/C39930001201
Citation: J. Chem. Soc., Chem. Commun., 1993,0, 1201-1203
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    Regio- and stereo-selective ring opening of epoxides with amide cuprate reagents

    Y. Yamamoto, N. Asao, M. Meguro, N. Tsukada, H. Nemoto, N. Sadayori, J. G. Wilson and H. Nakamura, J. Chem. Soc., Chem. Commun., 1993, 0, 1201
    DOI: 10.1039/C39930001201

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