Issue 5, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Construction of unusual metal clusters using dicarbon (C2) as a collar. Examples based on permetallabicyclo[2.2.0]hexane frameworks

Chris J. Adams,   Michael I. Bruce,   Brian W. Skelton  and  Allan H. White  

Abstract

The pentanuclear C2 complex [Ru5(µ5-C2)(µ-SMe)2(µ-PPh2)2(CO)11]1 is a source of novel cluster frameworks which incorporate the C2 ligand as a collar; this is exemplified by the structures of [FeRu5(µ6-C2)(µ-SMe)2(µ-PPh2)2(CO)14]2 and [Co4Ru5(µ10-C2)(µ3-SMe)2(µ-PPh2)2(µ-CO)7(CO)11]4, obtained from reactions between 1 and [Fe2(CO)9] or [Co2(CO)8], respectively.

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Article information

DOI
https://doi.org/10.1039/C39930000446
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 446-450

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Construction of unusual metal clusters using dicarbon (C2) as a collar. Examples based on permetallabicyclo[2.2.0]hexane frameworks

C. J. Adams, M. I. Bruce, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1993, 446 DOI: 10.1039/C39930000446

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