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Issue 5, 1993
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Construction of unusual metal clusters using dicarbon (C2) as a collar. Examples based on permetallabicyclo[2.2.0]hexane frameworks

Abstract

The pentanuclear C2 complex [Ru55-C2)(µ-SMe)2(µ-PPh2)2(CO)11]1 is a source of novel cluster frameworks which incorporate the C2 ligand as a collar; this is exemplified by the structures of [FeRu56-C2)(µ-SMe)2(µ-PPh2)2(CO)14]2 and [Co4Ru510-C2)(µ3-SMe)2(µ-PPh2)2(µ-CO)7(CO)11]4, obtained from reactions between 1 and [Fe2(CO)9] or [Co2(CO)8], respectively.

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Article type: Paper
DOI: 10.1039/C39930000446
Citation: J. Chem. Soc., Chem. Commun., 1993,0, 446-450
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    Construction of unusual metal clusters using dicarbon (C2) as a collar. Examples based on permetallabicyclo[2.2.0]hexane frameworks

    C. J. Adams, M. I. Bruce, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1993, 0, 446
    DOI: 10.1039/C39930000446

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