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Issue 20, 1993
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Silicone grease as a precursor to a pseudo crown ether ligand: crystal structure of [K+]3[K(Me2SiO)7+][InH(CH2CMe3)3]4

Abstract

The crystallization of K[InH(CH2CMe3)3] from heptane in the presence of silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-(Me2SiO)7 ligand; K+⋯ O distances range from 2.86(3) to 2.99(4)Å.

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Article type: Paper
DOI: 10.1039/C39930001577
Citation: J. Chem. Soc., Chem. Commun., 1993,0, 1577-1578
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    Silicone grease as a precursor to a pseudo crown ether ligand: crystal structure of [K+]3[K(Me2SiO)7+][InH(CH2CMe3)3]4

    M. R. Churchill, C. H. Lake, S. L. Chao and O. T. Beachley, J. Chem. Soc., Chem. Commun., 1993, 0, 1577
    DOI: 10.1039/C39930001577

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